The Ozone Hole

For nearly a billion years, ozone molecules in the atmosphere have protected life on Earth from the effects of ultraviolet rays.

The ozone layer resides in the stratosphere and surrounds the entire Earth. UV-B radiation (280- to 315- nanometer (nm) wavelength) from the Sun is partially absorbed in this layer. As a result, the amount of UV-B reaching Earth’s surface is greatly reduced. UV-A (315- to 400-nm wavelength) and other solar radiation are not strongly absorbed by the ozone layer. Human exposure to UV-B increases the risk of skin cancer, cataracts, and a suppressed immune system. UV-B exposure can also damage terrestrial plant life, single cell organisms, and aquatic ecosystems.

Credit:Center for Global Environmental Research, National Institute for Environmental Studies Japan

 In the past 60 years or so human activity has contributed to the deterioration of the ozone layer. 

NASA Graphic

Only 10 or less of every million molecules of air are ozone. The majority of these ozone molecules resides in a layer between 10 and 40 kilometers (6 and 25 miles) above the Earth's surface in  the stratosphere.

 Each spring in the stratosphere over Antarctica (Spring in the southern hemisphere is from September through November.), atmospheric ozone is rapidly destroyed by chemical processes. 

As winter arrives, a vortex of winds develops around the pole and isolates the polar stratosphere. When temperatures drop below -78°C (-109°F), thin clouds form of ice, nitric acid, and sulphuric acid mixtures. Chemical reactions on the surfaces of ice crystals in the clouds release active forms of CFCs. Ozone depletion begins, and the ozone “hole” appears. 

Over the course of two to three months, approximately 50% of the total column amount of ozone in the atmosphere disappears. At some levels, the losses approach 90%. This has come to be called the Antarctic ozone hole.

In spring, temperatures begin to rise, the ice evaporates, and the ozone layer starts to recover.

The Antarctic ozone hole was discovered in 1985 by British scientists Joesph Farman, Brian Gardiner, and Jonathan Shanklin of the British Antarctic Survey.

The ozone "hole" is really a reduction in concentrations of ozone high above the earth in the stratosphere. The ozone hole is defined geographically as the area wherein the total ozone amount is less than 220 Dobson Units. The ozone hole has steadily grown in size (up to 27 million sq. km.) and length of existence (from August through early December) over the past two decades.

After a series of rigorous meetings and negotiations, the Montreal Protocol on Substances that Deplete the Ozone Layer was finally agreed upon on 16 september 1987 at the Headquarters of the International Civil Aviation Organization in Montreal. 

NASA/NOAA satellite data showing the rise in stratospheric chlorine and corresponding decline in ozone layer thickness from 1979 to 1997. As stratospheric chlorine declined in response to enactment of the Montreal Protocol, the first stage of ozone recovery began.

The Montreal Protocol stipulates that the production and consumption of compounds that deplete ozone in the stratosphere--chlorofluorocarbons (CFCs),  halons, carbon tetrachloride, and methyl chloroform--are to be phased out by 2000 (2005 for methyl chloroform). Scientific theory and evidence suggest that, once emitted to the atmosphere, these compounds could significantly deplete the stratospheric ozone layer that shields the planet from damaging UV-B radiation.

 Man-made chlorines, primarily chloroflourobcarbons (CFCs), contribute to the thinning of the ozone layer and allow larger quantities of harmful ultraviolet rays to reach the earth.

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